Emendatio ex 18:28, 23 Decembris 2009 recensere 130.215.96.89 (disputatio) →‎Collectiones ← Differentia superior		Emendatio ex 18:29, 23 Decembris 2009 recensere abrogare 130.215.96.89 (disputatio) No edit summary Differentia proxima →
Linea 25: Quamobrem variae energiae, quae minimum iuxta varias condiciones impositas capiunt, per [[transformatio Legandreana\|transformationes Legandreanas]] definiuntur: Enthalpia: <math>H(S,P,N)=E(S,V,N)+PV</math> ubi <math>P</math> loco <math>V</math> fixatur; Energia libera ~~cannonica~~canonica: <math>F(T,V,N)=E(S,V,N)-TS</math> ubi <math>T</math> loco <math>S</math> fixatur; Energia libera Gibbs: <math>G(T,P,N)=E(S,V,N)-TS+PV</math> ubi <math>T,P</math> loco <math>S,V</math> fixantur; Energia libera ~~macrocannonica~~macrocanonica <math>\Psi (T,V,\mu)=E(S,V,N)-TS-\mu N</math> ubi <math>T, \mu </math> loco <math>S,N</math> fixantur. ==Collectiones== Physici praecipue tres collectiones statisticas definiunt quibus proprietates systematum thermodynamicorumex proprietatibus molecularum sive atomorum calculari possunt: Collectio ~~microcannonica~~microcanonica ubi <math>E, V \text{ et } N</math> fixantur Collectio ~~cannonica~~canonica ubi <math>T, V \text{ et } N</math> fixantur *Collectio ~~macrocannonica~~macrocanonica ubi <math> T, V \text{ et } \mu</math> fixantur <center> Linea 41: \| colspan="3" bgcolor="#C8D8FF" style="border-left:1px solid; border-right:1px solid; border-top:1px solid;" \| '''Collectiones :''' \|----- \| bgcolor="#C8D8FF" style="border-left:1px solid; border-top:1px solid;" \| [[Collectio microcanonica\|~~Microcannonica~~Microcnnonica]] \| bgcolor="#C8D8FF" style="border-left:1px solid; border-top:1px solid;" \| [[Collectio canonica\|~~Cannonica~~Canonica]] \| bgcolor="#C8D8FF" style="border-left:1px solid; border-right:1px solid; border-top:1px solid;" \| [[Collectio ~~macrocannonica~~macrocanonica\|~~Macrocannonica~~Macrocanonica]] \|----- \| style="border-left:1px solid; border-top:1px solid; background:#CCFFCC;" \| Variabiles fixae Linea 52: \| style="border-left:1px solid; border-top:1px solid; background:#CCFFCC;" \| Functio microscopica \| style="border-left:1px solid; border-top:1px solid;" \| <small> Numerus [[microstatus]] </small><br /><br /><math> \;W </math> \| style="border-left:1px solid; border-top:1px solid;" \| <small> Functio partitionis ~~cannonica~~canonica<br /><br /><math>Z = \sum_k e^{-\beta E_k}</math> \| style="border-left:1px solid; border-top:1px solid; border-right:1px solid;" \| <small> Functio partitionis ~~macrocannonica~~macrocanonica<br /><br /><math> z \ = \ \sum_k e^{ -\beta (E_k - \mu N_k ) } </math> \|----- Linea 62: \|}</center><noinclude> Collectio ~~microcannonica~~microcanonica utilis est ad multa theorema statistica demonstranda. Physici autem plerumque adhibent collectionem cannonicam ad res physicas calculandas, nisi cum de problematis quanticis tractandum est, ubi tunc oportet propter continuam particularum creationem et destructionem collectione macrocanonnica uti. ===Collectio microcanonica===

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